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March 2, 2007Angewandte Chemie International Edition371 citationsOpen Access

Metal‐Free Activation of CO2 by Mesoporous Graphitic Carbon Nitride

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FGFrédéric GoettmannATArne ThomasMAMarkus Antonietti

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Abstract

Doubly useful: The use of a mesoporous graphitic carbon nitride (mpg-C3N4) as a heterogeneous, metal-free catalyst enabled the direct activation of CO2 and the oxidation of benzene to phenol (see picture). The formed CO can be used in situ for subsequent reactions, as is shown for a Pauson–Khand reaction.

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Cite This Study

Goettmann et al. (2007) studied this question.

synapsesocial.com/papers/6a6337b6d5a927370109519dhttps://doi.org/10.1002/anie.200603478
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