March 1, 1999

A Simple Method to Prepare Head-to-Tail Coupled, Regioregular Poly(3-alkylthiophenes) Using Grignard Metathesis

RLRobert S. LoeweNorfolk State University SKSonya M. KhersonskyAlbert Einstein College of Medicine RMRichard D. McCulloughHudson Institute

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Abstract

Poly(3-alkylthiophenes) (PATs) exhibit promising electronic properties; however, their regioregular syntheses are only beginning to be developed. The authors describe a new method for the preparation of head-to-tail coupled (HT) PATs, in which methylmagnesium bromide is utilized to

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