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February 27, 2026Journal of Chemical & Engineering Data2 citations

Experimental Thermophysical Properties and Temperature Dependence of Four Non-Ionic Deep Eutectic Solvents

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JWJingwen WangAnhui UniversityFWFanjing WeiNorth University of ChinaQZQingqing ZhangJiangnan University

Key Points

  • This research aims to investigate the thermophysical properties and temperature dependence of four non-ionic deep eutectic solvents.
  • Prepared four non-ionic deep eutectic solvents using specific hydrogen-bond acceptors and donors at defined molar ratios.
  • Measured density, viscosity, surface tension, electrical conductivity, and melting point over the temperature range of 303.15–343.15 K.
  • Analyzed the temperature dependence of properties with empirical or Arrhenius-type correlations.
  • Found systematic variations in thermophysical properties with temperature.
  • Identified significant influence of molecular composition on non-ionic DES behavior.
  • Demonstrated potential of non-ionic DESs as low-viscosity and versatile solvents for chemical applications.

Abstract

Deep eutectic solvents (DESs) have emerged as promising alternatives to conventional solvents due to their tunable properties and potential environmental benefits. While most studies focus on ionic DESs, nonionic DESs remain less explored. In this work, four nonionic deep eutectic solvents (DESs) are prepared using diethylene glycol dimethyl ether or isoquinoline as hydrogen-bond acceptors (HBA) and cyclohexanecarboxylic acid, nonanoic acid, or 1-naphthylamine as hydrogen-bond donors (HBD) at specific molar ratios. Their fundamental thermophysical properties, including density, viscosity, surface tension, electrical conductivity, and melting point, are systematically measured over the temperature range of 303.15–343.15 K. The temperature dependence of all measured properties is quantitatively analyzed using appropriate empirical or Arrhenius-type correlations. The results provide insights into the influence of molecular composition on nonionic DES behavior, expanding the experimental database and highlighting their potential as low-viscosity, tunable, and versatile solvents for chemical engineering applications.

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Cite This Study

Wang et al. (2026) studied this question.

synapsesocial.com/papers/69a134dded1d949a99abe5f5https://doi.org/10.1021/acs.jced.5c00677
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