Electrolyte Effect on Electrocatalytic CO2 Reduction

Electrocatalytic CO2 reduction reaction shows great potential for converting CO2 into high-value chemicals and fuels at normal temperature and pressure, combating climate change and achieving carbon neutrality goals. However, the complex reaction pathways involve the transfer of multiple electrons and protons, resulting in poor product selectivity, and the existence of competitive hydrogen evolution reactions further increases the associated difficulties. This review illustrates the research progress on the micro mechanism of electrocatalytic CO2 reduction reaction in the electrolyte environment in recent years. The reaction pathways of the products, pH effects, cation effects and anion effects were systematically summarized. Additionally, further challenges and difficulties were also pointed out. Thus, this review provides a theoretical basis and future research direction for improving the efficiency and selectivity of electrocatalytic CO2 reduction reaction.