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Mn- and Sb-doped PbZrTiO3 (PMSZT) thin-film pyroelectric infrared (IR) detectors have been fabricated on c-oriented YB2Cu3O7−x (YBCO) thin films. The thin-film heterostructure detectors were prepared by pulsed laser deposition on LaAlO3 (100) substrates. The YBCO layer in the PMSZT/YBO heterostructure was used as an atomic template for the epitaxial growth of the PMSZT thin films, as well as a nonsuperconducting electrode and IR reflector in the detector. Mn and Sb doping was used to tune the Pb(Zr,Ti)O3 transition temperature to a lower value (Curie temperature of ∼170 °C), and hence, to modify the pyroelectric and dielectric properties of the pyroelectric material. The PMSZT IR detectors were examined as to their photovoltage and photocurrent in response to IR source temperature, detector temperature, and chopper frequency. The experimental results show that the detector has relatively high IR sensitivity with a detectivity D* of ∼4×108 cm Hz1/2/W, and is capable of operating from room temperature to ∼170 °C.
Wu et al. (Fri,) studied this question.