Compositionally-tuned epitaxial cubic MgxZn1−xO on Si(100) for deep ultraviolet photodetectors

We report on the epitaxial growth of wide-band-gap cubic-phase MgxZn1−xO thin films on Si(100) by pulsed-laser deposition and fabrication of oxide-semiconductor-based ultraviolet photodetectors. The challenges of large lattice and thermal expansion mismatch between Si and MgxZn1−xO have been overcome by using a thin SrTiO3 buffer layer. The heteroepitaxy of cubic-phase MgxZn1−xO on Si was established with epitaxial relationship of MgxZn1−xO(100)//SrTiO3(100)//Si(100) and MgxZn1−xO100//SrTiO3100//Si110. The minimum yield of the Rutherford backscattering ion channeling in MgxZn1−xO layer was only 4%, indicating good crystalline quality of the film. Smooth surface morphology with rms roughness of 0.6 nm was observed using atomic force microscopy. Photodetectors fabricated on Mg0.68Zn0.32O/SrTiO3/Si show peak photoresponse at 225 nm, which is in the deep UV region.