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Iridium dihydride complexes supported by PCP-type pincer ligands rapidly insert CO2 to yield κ2-formate monohydride products in THF. In acetonitrile/water mixtures, these complexes become efficient and selective catalysts for electrocatalytic reduction of CO2 to formate. Electrochemical and NMR spectroscopic studies have provided mechanistic details and structures of key intermediates.
Kang et al. (Tue,) studied this question.
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