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Using two-phase (water–toluene) reduction of AuCl4– by sodium borohydride in the presence of an alkanethiol, solutions of 1–3 nm gold particles bearing a surface coating of thiol have been prepared and characterised; this novel material can be handled as a simple chemical compound.
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Brust et al. (Sat,) studied this question.
www.synapsesocial.com/papers/69d9a3375e5bcb4e3b8375aa — DOI: https://doi.org/10.1039/c39940000801
Mathias Brust
Merryl Walker
Donald Bethell
Journal of the Chemical Society Chemical Communications
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