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The activation of CC double bonds for hydroboration may be achieved using rhodium complexes: e.g., the dioxaborole 1 undergoes preferential addition to the double bond when CIRh(PPh3)3 is added to the reaction mixture.
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Männig et al. (Tue,) studied this question.
synapsesocial.com/papers/69d9031db305d713c2beda3a — DOI: https://doi.org/10.1002/anie.198508781
Detlef Männig
Heinrich Nöth
University of Stuttgart
Angewandte Chemie International Edition in English
Ludwig-Maximilians-Universität München
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