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Oriented attachment is the key: Single crystalline ZnO nanorods with lengths up to 500 nm could be prepared in a stepwise manner from quasi-spherical nanoparticles. Only after the formation of pearl-chain-like structures (left), do the aggregated particles fuse upon heating to form nanorods (center and right).
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Claudia Pacholski
University of Potsdam
Andreas Kornowski
Universität Hamburg
Horst Weller
Karlsruhe Institute of Technology
Angewandte Chemie International Edition
Universität Hamburg
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Pacholski et al. (Tue,) studied this question.
synapsesocial.com/papers/6a087081113ba5b476de2c7d — DOI: https://doi.org/10.1002/1521-3773(20020402)41:7<1188::aid-anie1188>3.0.co;2-5