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We show how charge conservation and reciprocity can be built into local density or gradient approximations for density-density response functions (susceptibilities). We apply these ideas to derive from first principles a variant of the Rapcewicz-Ashcroft formula for the van der Waals interaction. We also discuss how improved formulas may be obtained.
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John F. Dobson
Griffith University
Bradley P. Dinte
Griffith University
Physical Review Letters
Griffith University
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Dobson et al. (Mon,) studied this question.
synapsesocial.com/papers/6a215a0abd959c3a83aba598 — DOI: https://doi.org/10.1103/physrevlett.76.1780