Solventless Synthesis of Copper Sulfide Nanorods by Thermolysis of a Single Source Thiolate-Derived Precursor

Organic monolayer protected Cu2S nanorods, 4 nm in diameter and 12 nm long, were synthesized using a novel solventless synthetic approach. Thermolytic degradation of a copper thiolate precursor at temperatures ranging from 140 to 200 degrees C produces Cu2S nanorods. Higher temperatures promote isotropic growth of spherical nanocrystals. X-ray diffraction and high-resolution TEM reveal that the nanorods exhibit a hexagonal Cu2S crystal structure, which in the bulk is ferroelectric. The appropriate reaction conditions produce nanorods that are size and shape monodisperse and organize into smectic superlattices. The extent of superlattice ordering and the appearance of extended strands of nanorods provide evidence for strong dipole-dipole coupling between Cu2S nanorods.