Zeta potential of Nafion molecules in isopropanol‐water mixture solvent

Abstract Structure of Nafion in isopropanol/water mixture solvent has been investigated using zeta potential. It was found that zeta potential of Nafion strongly depends on the concentration. When the concentration of Nafion varied from 0.5 to 1 wt %, zeta potential increased significantly from about 0 to −12 mV, corresponding to the change of structure of Nafion molecules from true solution to dispersion of aggregates. While the concentration is above 5 wt %, micelle‐like structure of Nafion aggregates was proposed. The dependence of zeta potential of Nafion on pH value at concentration of 5 wt % shows a nonmonotonic function and isoelectric point of Nafion‐Na of 8.0 was observed. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008