August 18, 1995
View Full PaperDiodelike Current–Voltage Curves for a Single Molecule–Tunneling Spectroscopy with Submolecular Resolution of an Alkylated, peri‐Condensed Hexabenzocoronene
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Abstract
The electronic properties of molecules can in some cases be elucidated by scanning tunneling microscopy and spectroscopy. The current–voltage characteristics through the aromatic core of a benzocoronene molecule (1), localized with submolecular resolution, are the same those of a diode, and are caused by the properties of a single molecule in contact with two electrodes. R = n-C12H25.