Wearable Magnetic Field Sensors for Flexible Electronics

Highly flexible bismuth Hall sensors on polymeric foils are fabricated, and the key optimization steps that are required to boost their sensitivity to the bulk value are identified. The sensor can be bent around the wrist or positioned on the finger to realize an interactive pointing device for wearable electronics. Furthermore, this technology is of great interest for the rapidly developing market of ­eMobility, for optimization of eMotors and magnetic bearings. The flourishing and eagerness of portable consumer electronics necessitates functional elements to be lightweight, flexible, and even wearable.1-7 Flexible devices advance from interconnects and individual sensing elements toward complex platforms consisting of communication and diagnostic components that fuel the vision of creating multifaceted, interactive,8 and wearable electronics.9 Next generation flexible appliances aim to become fully autonomous and will require ultra-thin and flexible navigation modules, body tracking, and relative position monitoring systems. Such devices fulfill the needs of soft robotics,10, 11 functional medical implants12, 13 as well as epidermal,9, 14 imperceptible,15, 16 and transient17, 18 electronics. Magnetic field sensors offer the possibility to sense and respond to external magnetic fields, which are considered as a vital feature when integrated into these novel kinds of electronic devices. Magnetosensorics is a versatile tool to assess mechanical movements not only in artificial devices like robotics but also in vivo. Foreseeable applications include real time monitoring of artificial joints or valves of the heart to diagnose early stages of dysfunctions. Key building blocks of navigation and position tracking devices are Hall effect sensors. Unfortunately, conventional semiconductor-based Hall sensors are about 400-μm-thick and rigid, limiting their direct applicability in flexible electronics. Here, we introduce a technology platform that allows us to fabricate highly flexible magnetic field sensors relying on the Hall effect. We combine inorganic functional nanomembranes with polymeric foils to achieve flexible sensing elements with a near bulk sensitivity of about −2.3 V (AT)−1. The flexible sensors fabricated on 100-μm-thick polyimide foils withstand severe mechanical deformations. We observe only a minor reduction in the sensor performance when bent into a radius of 6 mm, which is fully recovered in the flat state. We chose 100-μm-thick polyimide (PI) and 25-μm-thick polyether ether ketone (PEEK) foils to demonstrate the viability of our technology platform. Hall sensor elements are formed by depositing bismuth films via magnetron sputtering onto the PI and PEEK supports. These materials reveal exceptionally good mechanical, thermal, and chemical stability and are applied in state of the art consumer electronics. Bismuth-based Hall sensors19-22 bear several distinct advantages: i) Bi has the largest Hall coefficient of −(5–6) × 10−5 V cm (AT)−123 and thus the largest sensitivity among all (half-) metals,24 ii) the use of Bi allows surface depletion effects relevant for miniaturized semiconducting micro-Hall probes to be overcome; hence, Hall sensors with a sub-μm lateral size operating at room temperatures have been fabricated using Bi thin films,19, 20 and iii) Bi is readily processed using standard microelectronic facilities. Here, we deposit bismuth films onto electrical contacts, which are prepared on flexible foils (see Experimental Section for details). The resulting sensors can be bent on demand after their fabrication (Figure 1a). Adhering the flexible sensor to a finger (Figure 1b), creates an interactive pointing device and builds a component for wearable electronics (Figure 1c). By monitoring the sensor output, we visualize the relative position of the finger with respect to a permanent magnet (compare Figure 1d and e). Details on the conditioning electronics used here can be found in Figure S1 in the Supporting Information. Fabricated in this way, magnetic field sensing elements extend our cognition to magnetic fields that by no means can be detected by human beings. Such a concept is beneficial, for instance for safety applications where objects located in a dangerous environment that do not permit direct access by hand can be manipulated, or where unobtrusive and robust magnetic beacons can warn of imminent health risks. In addition to single sensors providing a point-like measurement of the magnetic flux density, we prepared 1D linear (Figure 1f) and 2D sensor arrays on commercial 150-μm-thick double layer flexible printed circuit (FPCs) boards, which defines the Hall-cross contact geometries and sensor arrangements. These sensor arrays can be applied to reconstruct a spatial and/or temporal profile of the magnetic field. For demonstration purposes, we exposed the flexible sensors array consisting of eight bismuth Hall sensors to the field of a permanent magnet (Figure 1g), which is swept forth and back along the sensor array. The maximum signal is achieved when the magnet is located above the respective sensor in the array (Figure 1h). Hence, by monitoring the shift of the maximum for each of the eight sensors, we can access the transient information on the evolution of the external magnetic field; in this particular case, we measure the displacement of a magnet as a function of time. This feature can be useful to monitor the magnetic field profile across a nonplanar area, e.g., the stator pole of an electrical machine to minimize losses and improve its overall efficiency (Figure S2 and S3, Supporting Information). In order to optimize the Hall performance of the flexible sensors, namely, the Hall sensitivity, a series of samples was prepared, where Bi films with different thicknesses in the range between 65 and 2000 nm were deposited onto flexible PEEK and PI foils. In addition, reference samples with nominally the same layer stack were prepared on rigid glass and Si substrates for comparison studies. Annealing is known to strongly influence the polycrystalline structure and hence the magnetoelectrical properties of deposited bismuth thin films.25, 26 Therefore, thermal treatment was applied to the sensors in order to determine the correct growth conditions that result in optimal Hall performance. Here, Bi films were deposited at substrate temperatures ranging from room temperature (RT) to 150 °C. Furthermore, post-fabrication annealing of the samples prepared at RT on polyimide foils was carried out at 250 °C for 3 h in air. The optimized Bi films with a thickness of 250 nm were lithographically patterned in the conventional Hall geometry as shown in Figure 1a and Figure 2a with an active area of the Hall sensor of 100 μm × 100 μm. Details on the patterning process can be found in the Experimental Section. Structural characterization using scanning electron micro­scopy (SEM) of the samples is shown in Figure 2. The overview image revealing the location of the 230-nm-thick bismuth Hall sensor annealed at 250 °C for 3 h is presented in Figure 2a showing the Hall cross as well as the position of electrical contacts. A magnified top view image taken at the Bi film is shown in Figure 2b. Note that the morphologies of the Bi layers grown on PEEK and polyimide foils are very similar (compare Figure 2b and 2c), indicating that the growth is almost independent of the choice of the polymeric substrate. The sample on PEEK foil is prepared without an additional post-fabrication annealing step and therefore exhibits a smaller lateral size of the Bi grains. The comparison of the top view images taken of the samples prepared on polymeric foils and rigid glass substrates suggests a more grainy morphology of the Bi functional layer prepared onto a flexible foil (compare Figure 2b, 2c, and 2e). To study the morphology in more detail, cross-sectional SEM images were taken. The cross-section cut is prepared using focused ion beam (FIB) etching in a dual-beam station. For these investigations, the samples were additionally covered with a carbon layer. In contrast to the information provided by the top view images, the cross-section study reveals better film quality at the local scale for samples prepared on polymeric membranes. Bismuth grains are regular and firmly in contact with each other, suggesting a good electrical conductivity of the samples. In agreement with reports on Bi growth on rigid substrates,26 the additional annealing step results in a substantial increase of the grain size to (860 ± 390) nm (on polyimide, Figure 2b1) as compared to the (180 ± 50) nm (on PEEK, Figure 2c1). The increase of the size of the Bi crystallites is expected to improve the Hall performance of the sensor elements as there will be less electron scattering events at the grain boundaries. However, at a larger scale of several micrometers, thicker grains can be clearly identified (compare Figure 2b1, 2c1 and 2e1). The presence of these sparsely distributed larger grains is not expected to adversely influence the overall electrical conductivity of the sample.22 The decrease of the Bi film thickness down to 65 nm results in a substantial increase of the granularity of the film with the appearance of voids (Figure 2d), which causes an increase of the overall sample resistance (see discussion below and Figure S4, Supporting Information). In contrast, when the thickness of the functional layer increases (Figure 2f), the crystallites grow in size and form a continuous layer. The magneto-electrical performance of the Bi-based Hall sensors prepared on flexible foils was characterized by measuring the Hall resistance of the samples positioned between the poleshoes of an electromagnet. Measurements were carried out at room temperature. The sensor sensitivity is defined as the slope of the Hall response (Hall voltage vs magnetic flux density) normalized to the value of the supply current. First, we note that the samples prepared on polyimide and PEEK foils qualitatively behave in the same way (Figure 3a), although the performance on polyimide is better. The deposition of the Bi film on flexible membranes at elevated temperatures has a strong influence on the resulting Hall sensitivity of the device. In particular, the preparation of a 100-nm-thick Bi thin film on polyimide foils at 150 °C allows the sensitivity to be increased by a factor of 2.8, compared with the samples prepared at RT, reaching a remarkable value of −1 V (AT)−1 (Figure 3a). A qualitatively similar result is obtained for Bi-based sensors on PEEK foils, although a slightly smaller increase of the sensitivity of 1.9 times is achieved (Figure 3a and Table S1, Supporting Information). We found that sensors deposited at 150 °C on flexible foils show a better performance than their rigid counterparts prepared on Si wafers. For rigid substrates, the maximum sensitivity of −0.6 V (AT)−1 was obtained for a 100-nm-thick sensor prepared at RT. The deposition at 100 °C results in a lowering of the Hall sensitivity, due to partial dewetting of the thin Bi film on the Si wafer. The electrical contact is lost for the sample prepared on a Si wafer at 150 °C. Figure 3b shows the modification of the performance of the Bi Hall sensors prepared on PEEK foils with the thickness of the Bi film. As the current density is increasing with the decrease of the film thickness, the sensitivity is increasing for thinner sensors reaching a maximum of about −0.4 V (AT)−1 for the sensor with a 280-nm-thick Bi layer. However, the sensitivity drops when the thickness of the Bi film is reduced below 200 nm. We attribute this finding to the modification of the morphology of the thin Bi films. Indeed, SEM images (Figure 2) reveal a substantial increase of the granularity of the film for a small thickness of Bi below 200 nm. This modification of the film morphology results in a substantial increase of the sensor resistance (Figure S4, Supporting Information). The latter is related to the enhanced scattering probability of the electrons at the grain boundaries when the mean free path of the electrons in Bi becomes comparable to the dimensions of the grains. Significant improvement of the sensor performance can be achieved by applying post-annealing to the samples prepared at RT. A comparison of the performance of as-prepared and post-annealed sensors is shown in Figure 3c. Treating 230-nm-thick Bi film prepared on polyimide foils at 250 °C for 3 h in air leads to a strong increase of sensitivity up to −(2.29 ± 0.01) V (AT)−1, which corresponds to the bulk value of −(2.2–2.6) V (AT)−1 recalculated for a Bi film of the same thickness.23 A similar sensitivity of −2 V (AT)−1 of the nano-structured bismuth sensors fabricated for scanning Hall microscopy on plastic cantilevers made of SU-8 was previously reported by Boero et al.27 Although the sensors are prepared on polymeric membranes, they are operational in a wide temperature range. The temperature dependence of the Hall response (Figure S5, Supporting Information) shows that the sensors are stable in a consumer temperature range (from −20 °C to 80 °C) with a temperature coefficient of the sensor's sensitivity of about 1 mV (A T K)−1. To investigate their bending performance, flexible sensor elements were mounted on sample holders with concave curvatures of radii varying from 32 mm down to 6 mm. From geometric considerations, these curvatures correspond to strain values in the bismuth film of 0.24% and 1.25%, respectively. Unbent, the sensor reveals a sensitivity of −(0.54 ± 0.01) V (AT)−1, which corresponds to the maximum value for the as-prepared sensing elements on the polyimide foils (200-nm-thick Bi film). The sensor response was measured in the planar, bent and then again in the planar arrangement for each radius of curvature (Figure 3d, inset). In the flat state, the sensor response remained at the initial sensitivity even after bending into a radius of 6 mm. We did not observe any degradation in sensor performance even after 50 bending cycles to a radius of 8 mm. For smaller radii, only a minor decay in sensitivity is observed (Figure 3d) and the performance remains at a high value of about −0.47 V (AT)−1, which is recovered in full after the sensor is re-measured in the flat arrangement (inset in Figure 3d). In conclusion, we fabricated flexible bismuth Hall sensors on polymeric PEEK and polyimide foils and identified key optimization procedures which are required to boost the sensitivity of the flexible sensors to the bulk value. The sensor can be bent around the wrist or positioned on the finger to realize an interactive pointing device that visualizes the relative position of the finger with respect to a magnetic field, thus creating a unique feedback element for wearable electronics. The optimized sensors possess a remarkable sensitivity of about −2.3 V (AT)−1. We demonstrated that flexible sensors withstand severe mechanical deformations and can be bent into radii of 6 mm with only a minor reduction in sensor performance. Moreover, no degradation of the sensor performance was observed after 50 bending cycles. Apart from flexible and wearable consumer electronics, thin and bendable Hall sensors are of great interest for integration into electrical machines and drives. Featuring a flat and flexible design, they can be positioned inside the typically curved and narrow (<500 μm) air gaps between rotor and stator (Figure S2 and S3, Supporting Information), in order to provide a direct magnetic field measurement, which is not feasible with current chip-based rigid sensing elements. Such measurements are especially useful for the optimization of eMotor designs and for the rapidly developing market of eMobility, since they help to improve the dynamical performance (stiffness and damping) as well as the positioning accuracy of magnetic bearing systems.28, 29 Fabrication of Hall Sensors on Polyimide and PEEK Foils: The structuring processes were carried out by means of optical lithography and lift-off techniques. A commercial image reversal resist (AZ 5214 E) was spun onto the flexible substrate (4000 rotations per min, 35 s). The resist was dried in a convection oven at a temperature of 90−95 °C for 30 min. The resist was exposed at 365 for a reversal process was at ± °C for 20 min. The is exposed for 30 and using for this a profile with is in the layer. The flexible substrate was covered by a layer using thermal process with deposition of nm and nm for and respectively. In a lithography a lift-off for the Bi Hall-cross is These patterned flexible foils were in the deposition where bismuth films of different thickness ranging from 65 up to 2000 nm were grown in the deposition nm was used as a at a partial of 1 × The deposition of Bi films was carried out at room temperature or at elevated temperatures up to 150 as in the Fabrication of Hall Sensors on we used 150-μm-thick double layer flexible with a path that defines the of the Hall elements. for single Hall elements (Figure Supporting Information), as well as for 1D sensor arrays (Figure 1f) were and First, we deposit a layer onto the and thickness of 35 μm) to a good of Bi films to the polymeric membranes. Bi layers are grown at room temperature using magnetron deposition nm and Bi films are deposited the in the top layer of the as shown in the of Figure in the Supporting Information. this fabrication the electrical of the Bi sensing element is the deposition The thickness of the Bi layers is to to the of the contacts. of Hall The temperature dependence of the Hall response is of the the performance of the The Hall effect in as well as in any or semiconducting is temperature due to a reduction of the with in a Figure in the Supporting shows the series of Hall from a Bi Hall cross prepared on PEEK measured at different temperatures by means of a As typically observed for the Hall the sensitivity of the sensors becomes smaller with an increasing temperature due to the decrease of the The slope of the linear shown in the a value of the temperature coefficient of the sensor's sensitivity of about 1 mV (A T K)−1. The temperatures in this a range for and consumer electronics. for Magnetic The contact of the sensor was to a with to the of the The electrical was by a The sensor was to the device (Figure S1, Supporting Information) using a flat in measurement The sensor's response to an applied magnetic field was detected by measuring the in the Hall voltage a The sensor was by a current of Figure S1, Supporting Information), by a current circuit on the device. The voltage signal from the sensor was by an with a defined by resistance (Figure S1, Supporting Information). the signal to the on and of each can be Figure S1, Supporting Information) in order to the sensor signal to an range of the to in a of the device. The was processed in the and on a of 8 the of between the magnetic sensor on the finger and the for and Flexible Hall sensors are of great interest not only in the field of consumer electronics. In the rapidly developing market of there is a strong demand for novel sensor to the way toward more and designs of electrical This the measurement of the magnetic fields in curved and air gaps μm) between the rotor and In order to this sensor on the Hall effect have to be which are less than 200 μm and up fields of in electrical machines and where conventional rigid semiconductor-based Hall sensors the sensor signal as a feedback in of active magnetic an improvement of the dynamical performance (stiffness and damping) as well as a more positioning accuracy of the magnetic can be 29 Furthermore, the flux of active magnetic can fabrication by position sensing or increase their as a for and applications or in To demonstrate the full of our platform in this we prepared an of the Hall sensors onto double layer as shown in Figure in the Supporting Information. The sensor is mounted to the curved of the stator of an electrical (Figure Supporting Information) or active magnetic bearing (Figure S3, Supporting Information), into the narrow air between rotor and stator (Figure Supporting Information). The flexible Hall sensors are to monitor the magnetic flux density in a active magnetic bearing (Figure Supporting Information). Figure in the Supporting shows the magnetic bearing consisting of the a position measurement mechanical bearing as well as an to the with a magnetic air of μm and a stator pole surface of 20 mm × mm the up to Table S2 in the Supporting the of the magnetic provide a permanent magnetic a of the by flux of and flux (Figure Supporting Information). Figure Supporting the of the magnetic flux density in the air when the rotor was from the initial The measurement of the rotor carried out using a sensor providing a of about 50 is that the Hall signal shows the response to the function of the rotor The presented and the sensitivity of up to V after with a of in the full range up to T demonstrate the of flexible bismuth Hall sensors to be applied for flux density measurements in magnetic and electrical measurements were using patterned sensors on polyimide foils (Figure 1a). The for the access to the active magnetic bearing for the deposition of Bi films. This is in via the and of as well as by the the and As a to our and this information by the Such materials are and be for but are not or from information than be to the The is not for the or of any information by the than be to the for the