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Plants metabolize carbon dioxide photosynthetically either through a 3-carbon (Calvin) or 4-carbon pathway. Most plants are of the C-3 type; C-4 plants are primarily grasses adapted to hot, arid environments. Since C-4 plants have a higher 13 C/ 12 C ratio than C-3 plants, animals and humans with a significant C-4 plant food-intake will have higher 13 C/ 12 C ratios as well. Maize is a C-4 plant, hence maize cultivators living in predominantly C-3 plant environments should show significant isotopic differences from local hunter-gatherers in their skeletal remains; the importance of maize in their diet should also be measurable. The practicability of this method is demonstrated for New York State archaeological materials and wider implications are mentioned.
Vogel et al. (Fri,) studied this question.