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Dehydration induces a crystal-to-crystal transformation of a 3D interpenetrated metal-organic framework into a 2D square-grid structure that exhibits dynamic expansion and shrinkage triggered by clathrate formation with CO2 molecules. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

October 25, 2006

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Novel Expansion/Shrinkage Modulation of 2D Layered MOF Triggered by Clathrate Formation with CO2 Molecules

AKAtsushi KondoOita University HNHiroshi NoguchiKyushu University SOShunsuke OhnishiHokkaido University

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Abstract

Crystal-to-crystal transformation from a 3D interpenetrated-type MOF Cu (BF (4) ) (2) (bpy) (H (2) O) (2) (bpy) (1) to a 2D square-grid-type Cu (BF (4) ) (2) (bpy) (2) (2) (bpy = 4, 4'-bipyridine) was observed. It was derived from dehydration and confirmed by in situ FT-IR, TG, and elemental analysis. Moreover, we elucidate the novel expansion/shrinkage dynamic modulation of 2 triggered by clathrate formation with gas molecules.

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Novel Expansion/Shrinkage Modulation of 2D Layered MOF Triggered by Clathrate Formation with CO2 Molecules

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