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Activated carbon was prepared from olive stones by physical activation using water vapor at 750 °C. Textural, morphology and surface chemistry characterizations were achieved (nitrogen adsorption, SEM, FTIR and TPD–MS). NO 2 adsorption was performed for different inlet gas compositions and temperatures. NO 2 may adsorb directly on the oxygenated surface groups, and can also be reduced to NO. Therefore, a second NO 2 molecule adsorbs on the oxygen left on the carbon surface. TPD performed after NO 2 adsorption showed the presence of various surface groups. The adsorption capacity was about 131 mg/g, which is higher than with several activated carbon prepared from classical lignocellulosic biomass. NO 2 reduction into NO decreased with increasing the inlet oxygen concentration. In contrast, a slight decrease in the NO 2 adsorption capacity was observed with increasing temperature. It seems that the activated carbons prepared from olive stones by steam activation could be used as efficient adsorbents for NO 2 removal.
Ghouma et al. (Sat,) studied this question.