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A strategy used to design high capacity (>200 mAh g−1), Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries is discussed. The advantages of the Li2MnO3 component and its influence on the structural stability and electrochemical properties of these layered xLi2MnO3·(1 − x)LiMO2 electrodes are highlighted. Structural, chemical, electrochemical and thermal properties of xLi2MnO3·(1 − x)LiMO2 electrodes are considered in the context of other commercially exploited electrode systems, such as LiCoO2, LiNi0.8Co0.15Al0.05O2, Li1+xMn2−xO4 and LiFePO4.
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Michael M. Thackeray
Sun-Ho Kang
Christopher S. Johnson
Journal of Materials Chemistry
Argonne National Laboratory
Michigan Technological University
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Thackeray et al. (Mon,) studied this question.
www.synapsesocial.com/papers/69de051f1d9bba5129b0bde4 — DOI: https://doi.org/10.1039/b702425h
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