September 1, 1997
View Full PaperA Molecular Railroad with Large Pores: Synthesis and Structure of Ni(4,4‘-bpy)2.5(H2O)2(ClO4)2·1.5(4,4‘-bpy)·2H2O
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Abstract
The hydrothermal reaction of Ni(II) and the rodlike 4,4‘-bipyridine ligand yields an extended 1-D noninterpenetrated open framework resembling a railroad with large pores of 11 × 11 Å aperture. (4,4‘-Bipyridine is illustrated as lines, and Ni atoms are at the intersections.)