Apatite weathering and the Phanerozoic phosphorus cycle

Research Article| July 01, 2000 Apatite weathering and the Phanerozoic phosphorus cycle Michael W. Guidry; Michael W. Guidry 1Department of Oceanography, School of Ocean and Earth Science and Technology, University of Hawaii, Honolulu, Hawaii 96822, USA Search for other works by this author on: GSW Google Scholar Fred T. Mackenzie Fred T. Mackenzie 1Department of Oceanography, School of Ocean and Earth Science and Technology, University of Hawaii, Honolulu, Hawaii 96822, USA Search for other works by this author on: GSW Google Scholar Geology (2000) 28 (7): 631–634. https://doi.org/10.1130/0091-7613(2000)282.0.CO;2 Article history received: 20 Jan 2000 rev-recd: 27 Mar 2000 accepted: 09 Apr 2000 first online: 02 Jun 2017 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn MailTo Tools Icon Tools Get Permissions Search Site Citation Michael W. Guidry, Fred T. Mackenzie; Apatite weathering and the Phanerozoic phosphorus cycle. Geology 2000;; 28 (7): 631–634. doi: https://doi.org/10.1130/0091-7613(2000)282.0.CO;2 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyGeology Search Advanced Search Abstract Despite widespread debate in the literature, there is still considerable uncertainty concerning which nutrient ultimately controls marine net ecosystem production (NEP) over geologic time. Geochemical arguments suggest that phosphorus is the culprit. The weathering of apatite, the primary phosphorus sink in Earth's exosphere, controls long-term phosphorus availability. If phosphorus is the ultimate controlling nutrient over geologic time scales, then long-term marine NEP is coupled to the release of phosphorus from apatite weathering. The most abundant apatite compositions found in nature are igneous fluorapatite and marine sedimentary carbonate fluorapatite. Sparse data exist on how these compositions dissolve under Earth's surface conditions. To demonstrate a need for these data and their application, we present a kinetic treatment of existing data, augmented by new results. We then use these results in a weathering model designed to illustrate the control exerted by temperature (via activation energy) and surface area on the phosphorus flux from apatite dissolution during the Phanerozoic. Our conclusion is that activation energy, and hence temperature, and apatite surface area are important parameters governing the phosphorus flux from apatite weathering and therefore marine NEP during Phanerozoic time. You do not have access to this content, please speak to your institutional administrator if you feel you should have access.