Optically induced conductivity changes in discharge-produced hydrogenated amorphous silicon

Long exposure to light decreases the photoconductivity and dark conductivity of some samples of hydrogenated amorphous silicon (a-Si : H). Annealing above ∼150 °C reverses the process. The effect occurs in the bulk of the films, and is associated with changes in density or occupation of deep gap states. High concentrations of P, B, or As quench the effect. Possible models involving hydrogen bond reorientation at a localized defect or electron-charge transfer between defects are discussed. An example is shown where these conductivity changes do not affect the efficiency of an a-Si : H solar cell.