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A new calorimeter has been developed and the enthalpy of solution of methanol, ethanol, propan-1-ol, propan-2-ol, butan-1-ol, and 2- methylpropan-2-ol, in water to low concentrations, measured between 5° and 35°. In all cases, the results can be adequately represented by a quadratic dependence of heat of solution on temperature. The results have been compared qualitatively with the data for the hydrocarbons.
Alexander et al. (Sat,) studied this question.