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Abstract Perturbation methods are employed to calculate a wide range of atomic parameters relating to the ground states of the helium iso-electronic sequence, the unperturbed eigenfunctions being products of screened hydrogenic orbitals. The screening constant enters as a disposable parameter. A means of choosing it is described which yields different values for different atomic properties. It is shown quantitatively that the simple calculations involved thereby lead to results of high accuracy.
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A. Dalgarno
Harvard University
A L Stewart
Queen's University Belfast
Proceedings of the Royal Society of London A Mathematical and Physical Sciences
Queen's University Belfast
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Dalgarno et al. (Tue,) studied this question.
synapsesocial.com/papers/6a1b0c551d5655a6414c630f — DOI: https://doi.org/10.1098/rspa.1960.0170