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A homochiral microporous hydrogen-bonded organic framework (HOF-2) based on a BINOL derivative has been synthesized and structurally characterized to be a uninodal 6-connected 3 (3) 5 (5) 6 (6) 7 network. This new HOF exhibits not only a permanent porosity with the BET of 237. 6 m (2) g (-1) but also, more importantly, a highly enantioselective separation of chiral secondary alcohols with ee value up to 92% for 1-phenylethanol.
Li et al. (Fri,) studied this question.