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Direct measurement of vertical binding energy of a hydrated electron | Synapse

January 1, 2010

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Direct measurement of vertical binding energy of a hydrated electron

YTYing TangSouthwest University HSHuan ShenHuazhong Agricultural University KSKentaro SekiguchiJapan Atomic Energy Agency

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Abstract

We present the first measurement of the vertical binding energy (VBE) of a hydrated electron in bulk water by the time-resolved photoelectron spectroscopy (TRPES) of the charge-transfer-to-solvent (CTTS) reaction in aqueous NaI solution. Our best estimate of VBE is 3.27 +/- 0.10 eV for H(2)O and 3.20 +/- 0.10 eV for D(2)O.

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Tang et al. (Fri,) studied this question.

synapsesocial.com/papers/6a0f1a5c14089a5783bdb69f https://doi.org/https://doi.org/10.1039/b925741a