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SmI2 is a versatile reagent now widely used in organic chemistry. Despite the wealth of literature on the subject, the mechanisms of some SmI2-mediated reactions are still uncertain and the role of additives and cosolvents is poorly understood. This review covers the use of SmI2-mediated cyclization reactions in natural product synthesis. The use of the full armory of ring-forming reactions conducted by the reagent is outlined. Focus is on the most challenging targets, such as Taxol, gambierol, and diazonamide A.
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Edmonds et al. (Thu,) studied this question.
www.synapsesocial.com/papers/69dd5cbafb7610310c102649 — DOI: https://doi.org/10.1021/cr030017a
David J. Edmonds
Derek Johnston
David J. Procter
Chemical Reviews
University of Glasgow
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