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Introduction of functionalized C1, C2, and C3 units to imines was achieved by using the dimethylzinc-air-initiated alpha-alkoxyalkyl radical addition as a key reaction. The addition to a Cdouble bondN double bond chemoselectively occurred in the presence of a Cdouble bondO double bond, which is one of the advantages of this radical addition reaction over ionic addition reactions.
Yamada et al. (Sat,) studied this question.
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