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The cellular method of constructing wave functions for electrons in crystals developed principally by Wigner and Seitz and Slater is tested by applying it to an artificial crystal in which the potential is constant. Knowledge of the exact solutions for this case, plane waves, shows that the cellular method is quite accurate in the first Brillouin zone but may be in error by a factor of two in the second. Hence calculations of occupied levels in Li and Na are probably quite good; for Cu, Ca, diamond, LiF, and NaCl the errors will be larger. Calculations of excited states are likely to be very much in error. The accuracy of the cellular method is shown to improve very slowly with increasing number of continuity conditions.
W. Shockley (Fri,) studied this question.