Mass and Elemental Composition of Fine and Coarse Particles in Six U.S. Cities

Abstract Inhalable particulate matter (IP) samples have been collected in six U.S. cities in conjunction with an air pollution health study. The IP were collected using dichotomous virtual impactors in two size ranges: fine particles (FP) having aerodynamic diameter (da) <2.5 μm, and coarse particles (CP) with 2.5 μm < da < 15 μm. The mass measurements were determined by beta-gauge attenuation. The elemental composition of the FP and CP were determined by X-ray fluorescence. The means and distributions for FP and CP and selected elemental data highlight the similarities and differences that exist among these cities in the health study. Examining the temporal variations gives additional information on the meteorology and sources influencing the FP and CP fractions of Inhalable particle mass. Differences in the concentration (and ratios) of selected elements have indicated the varying presence of crustal, steel industry, automotive, oceanic and fuel combustion sources in these cities. The noted variation in the concentrations and character of ambient aerosols in these cities are pertinent to interpreting differences in population exposures.