Effect of Rare Fluctuations on the Thermalization of Isolated Quantum Systems

We consider the question of thermalization for isolated quantum systems after a sudden parameter change, a so-called quantum quench. In particular, we investigate the prerequisites for thermalization, focusing on the statistical properties of the time-averaged density matrix and of the expectation values of observables in the final eigenstates. We find that eigenstates, which are rare compared to the typical ones sampled by the microcanonical distribution, are responsible for the absence of thermalization of some infinite integrable models and play an important role for some nonintegrable systems of finite size, such as the Bose-Hubbard model. We stress the importance of finite size effects for the thermalization of isolated quantum systems and discuss two scenarios for thermalization.