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Summary The equation of state PV = - a/V + RT(1 - y)-4 is shown to be considerably better at high densities than van der Waals' equation PV = - a/V + RT(1 - 4y)-1 and to be equal in accuracy to two other slightly more complicated equations for PV.
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E. A. Guggenheim (Fri,) studied this question.
www.synapsesocial.com/papers/6a06f556bbfaefe091d3c1f9 — DOI: https://doi.org/10.1080/00268976500100261
E. A. Guggenheim
Molecular Physics
University of Reading
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