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Light, inexpensive, effective: Nanostructured Co(3)O(4) clusters (see picture) in mesoporous silica are the first example of a nanometer-sized multielectron catalyst made of a first-row transition-metal oxide that evolves oxygen from water efficiently. The nanorod bundle structure of the catalyst results in a very large surface area, an important factor contributing to the high turnover frequency.
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Feng Jiao
Washington University in St. Louis
Heinz Frei
Berkeley College
Angewandte Chemie International Edition
University of California, Berkeley
Lawrence Berkeley National Laboratory
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Jiao et al. (Wed,) studied this question.
synapsesocial.com/papers/6a1a779d49c3147e1045ab55 — DOI: https://doi.org/10.1002/anie.200805534