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Life RAFT: A bulky methacrylate monomer, triphenylmethyl methacrylate (TrMA), was polymerized with reversible addition-fragmentation chain transfer (RAFT) agents. Stereogradient polymers in which the isospecificity increased spontaneously as the monomer concentration decreased were formed by a polymerization-depolymerization equilibrium that can convert a less stable growing polymer terminal into a more stable form (see picture).
Ishitake et al. (Wed,) studied this question.