January 1, 1998

A new synthesis of benzoporphyrins using 4,7-dihydro-4,7-ethano-2H-isoindole as a synthon of isoindole

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Abstract

Heating 4,7-dihydro-4,7-ethano-2H-isoindole at 200 °C induces the retro-Diels–Alder reaction to give isoindole in essentially quantitative yield, which can be applied to a new synthesis of tetrabenzoporphyrins and monobenzoporphyrins.

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Ito et al. (Thu,) studied this question.

www.synapsesocial.com/papers/69d9b5a600ab073a278373c2 — DOI: https://doi.org/10.1039/a803656j

Authors

Satoshi Ito

Takashi Murashima

Noboru Ono

Journals

Chemical Communications

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A new synthesis of benzoporphyrins using 4,7-dihydro-4,7-ethano-2H-isoindole as a synthon of isoindole

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Abstract

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