May 12, 2015
View Full PaperCobalt(III)‐Catalyzed Aryl and Alkenyl CH Aminocarbonylation with Isocyanates and Acyl Azides
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Abstract
Abstract Expedient CH aminocarbonylations of unactivated (hetero)arenes and alkenes were accomplished with a cobalt(III) catalyst that shows high functional group tolerance. The CH functionalization occurred with excellent chemo‐, site‐, and diastereoselectivity and enabled step‐economical reactions with isocyanates or acyl azides.