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Reaction of pyridine with well defined magnesium hydride species results in heterocycle dearomatisation by a hydride transfer which occurs with the formation of magnesium compounds containing 1,2- and 1,4-dihydropyridide anions as the respective kinetic and thermodynamic products.
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Hill et al. (Fri,) studied this question.
www.synapsesocial.com/papers/69da70e1a6045d71bfa3cbe3 — DOI: https://doi.org/10.1039/c0dt01246g
Michael S. Hill
D.J. MacDougall
Mary F. Mahon
Dalton Transactions
University of Bath
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