Self‐Template‐Directed Synthesis of Porous Perovskite Nanowires at Room Temperature for High‐Performance Visible‐Light Photodetectors

The unique optoelectronic properties and promising photovoltaic applications of organolead halide perovskites have driven the exploration of facile strategies to synthesize organometal halide perovskites and corresponding hybrid materials and devices. Currently, the preparation of CH3 NH3 PbBr3 perovskite nanowires, especially those with porous features, is still a great challenge. An efficient self-template-directed synthesis of high-quality porous CH3 NH3 PbBr3 perovskite nanowires in solution at room temperature using the Pb-containing precursor nanowires as both the sacrificial template and the Pb(2+) source in the presence of CH3 NH3 Br and HBr is now presented. The initial formation of CH3 NH3 PbBr3 perovskite layers on the surface of the precursor nanowires and the following dissolution of the organic component of the latter led to the formation of mesopores and the preservation of the 1D morphology. Furthermore, the perovskite nanowires are potential materials for visible-light photodetectors with high sensitivity and stability.