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Quick on the uptake: Palladium nanoparticles were fabricated simply by immersing Zn (3) (ntb) (2) (EtOH) (2) 4 EtOH (n) (1) in an MeCN solution of Pd (NO (3) ) (2) at room temperature, without any extra reducing agent. 3 wt % PdNPs@1 (0. 54+) (NO (3) (-) ) (0. 54) significantly increase H (2) uptake capacities, both at 77 K and 1 bar and at 298 K and high pressures (see picture, red curve) compared to Zn (3) (ntb) (2) (n) (black). ntb = 4, 4', 4''-nitrilotrisbenzoate.
Cheon et al. (Tue,) studied this question.
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