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The structure and function of the Ag cocatalyst in Ag loaded Ga2O3 photocatalysts for photocatalytic CO2 reduction with water were investigated. It was found that around 1 nm sized Ag clusters had strong interactions with the Ga2O3 surface and promoted the formation of bidentate formate species as the reaction intermediate for the CO production.
Yamamoto et al. (Thu,) studied this question.
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