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Recent work shows that nanoparticulate and amorphous molybdenum and tungsten sulfide materials are active catalysts for hydrogen evolution in aqueous solution. These materials hold promise for applications in clean hydrogen production technologies. In this perspective, the syntheses, structures and catalytic activities of nanoparticulate MoS2 and WS2, incomplete cubane-type Mo3S44+ and amorphous MoSx films are summarized, compared, and discussed.
Merki et al. (Sat,) studied this question.
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