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Photocatalytic oxygenation of benzene to phenol occurs under visible-light irradiation of 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) in an oxygen-saturated acetonitrile solution of benzene and tert-butyl nitrite. The photocatalytic reaction is initiated by photoinduced electron transfer from benzene to the triplet excited state of DDQ.
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Kei Ohkubo
Osaka University of Economics
Atsushi Fujimoto
Icahn School of Medicine at Mount Sinai
Shunichi Fukuzumi
Kanazawa University
Journal of the American Chemical Society
The University of Osaka
Ewha Womans University
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Ohkubo et al. (Thu,) studied this question.
synapsesocial.com/papers/69de841a4838c5c0bab0c0b6 — DOI: https://doi.org/10.1021/ja402303k
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