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The pre-H 2 O treatment and Al 2 O 3 film growth under a two-temperature-regime mode in an oxygen-deficient atomic layer deposition (ALD) chamber can induce n-type doping of graphene, with the enhancement of electron mobility and no defect introduction to graphene. The main mechanism of n-type doping is surface charge transfer at graphene/redox interfaces during the ALD procedure. More interestingly, this n-type doping of graphene is reversible and can be recovered by thermal annealing, similar to hydrogenated graphene (graphane). This technique utilizing pre-H 2 O treatment and an encapsulated layer of Al 2 O 3 achieved in an oxygen-deficient ALD chamber provides a simple and novel route to fabricate n-type doping of graphene.
Zheng et al. (Thu,) studied this question.