Ternary‐Blend Polymer Solar Cells Combining Fullerene and Nonfullerene Acceptors to Synergistically Boost the Photovoltaic Performance

A ternary-blend strategy is presented to surmount the shortcomings of both fullerene derivatives and nonfullerene small molecules as acceptors for the first time. The optimal ternary device shows a high power conversion efficiency (PCE) of 10.4%. Moreover, a significant enhancement in PCE (≈35%) relative to both of the binary reference devices, which has never been achieved before in high-efficiency ternary devices, is demonstrated.