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. Aromatic acids can be selectively transformed within one step either to bis-difluoromethylated alcohols or to difluorinated ketones depending on the particular reaction conditions. For bulky α-branched carboxylic acids, only ketones are produced.
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Trifonov et al. (Fri,) studied this question.
www.synapsesocial.com/papers/6a03df70ac14ad449f2b30ac — DOI: https://doi.org/10.1021/acs.orglett.7b02601
Alexey L. Trifonov
Vitalij V. Levin
Марина И. Стручкова
Organic Letters
N.D. Zelinsky Institute of Organic Chemistry
D. Mendeleyev University of Chemical Technology of Russia
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