Mechanism and modeling of polyvinylpyrrolidone (PVP) facilitated synthesis of silver nanoplates

Silver triangular nanoplates (AgTNP) present unique surface plasmonic and catalytic properties depending upon the thickness and edge length. AgTNP are synthesized in a kinetically controlled growth process, by and large, using the polymer poly-vinylpyrrolidone (PVP) as a reductant. In this work, we present a systematic study to uncover the effect of the molecular weight (MW) of PVP and the PVP to silver salt (AgNO3) molar ratio (P : S) on the physical dimensions of AgTNP. The edge length of AgTNP shows a non-monotonic variation with respect to P : S for all MWs. Based on several control experiments, a kinetic mechanism is proposed and a mathematical model is developed to explain the formation of AgTNP. The elementary processes of the model include the reduction of Ag+ by the -OH group in PVP, followed by instantaneous nucleation. This phase is then followed by a slow reduction of Ag+ and growth of the nuclei to AgTNP. The model shows a reasonable agreement with experiments on the non-monotonic variation of edge length of AgTNP with respect to P : S, as well as on the temporal evolution of the edge length.