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The hyperbranched polymers have drawn intensive attention in the design of macromolecules and functional materials because of their unique physical and chemical properties resulting from the branched architecture and the high number of functional groups. In the present study, by means of light scattering, viscosimetry, thermomechanical analysis, tensile stress-strain, mechanical loss tangent and water vapor permeability measurements, we demonstrate the hierarchical macromolecular organization of organoboron polyurethanes synthesized using sterically hindered amino ethers (AEBA) of boric acid. It is shown that the water vapor permeability of polyurethanes obtained on the basis of sterically hindered aminoethers of boric acid is due to the peculiarities of the chemical structure of AEBA, which can exhibit an ionomeric nature and the presence of steric hindrances created in the hyperbranched structure of AEBA, which can lead to an increase in free volume in such polyurethanes.
Давлетбаева et al. (Tue,) studied this question.