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Abstract Three isostructural covalent organic frameworks (COFs) with either methoxyl, hydroxyl, or both groups on the channel wall, are synthesized and served as metal‐free heterogeneous catalysts for chemical fixation of CO 2 . Among them, the COF decorated with both hydroxyl and methoxyl groups named OMe‐OH‐TPBP‐COF exhibits the highest catalytic activity and efficiency for CO 2 cycloaddition under mild conditions.
Yang et al. (Thu,) studied this question.
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