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pyranosylations employing easily accessible acetonide-protected donors. A wide variety of alcohol nucleophiles, including complex natural products, glycosides, and amino acids were β-mannosylated and β-rhamnosylated successfully using an operationally simple protocol under mild and neutral conditions. Less nucleophilic acceptors such as phenols were also glycosylated efficiently in excellent yields and with high β-selectivities.
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Qiuhan Li
Samuel M. Levi
Eric N. Jacobsen
Journal of the American Chemical Society
Harvard University
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Li et al. (Fri,) studied this question.
www.synapsesocial.com/papers/6a0063ff6be84a7ac8857413 — DOI: https://doi.org/10.1021/jacs.0c04255