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1,2-Aryl migration of α,α-diaryl tertiary azides was achieved by using the catalytic system of FeCl2/N-heterocyclic carbene (NHC) SIPr·HCl. The reaction generated aniline products in good yields after one-pot reduction of the migration-resultant imines.
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Kai‐Jie Wei
Tonghao Yang
Qing Chen
Chemical Communications
Lanzhou University
State Key Laboratory of Applied Organic Chemistry
Lanzhou City University
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Wei et al. (Wed,) studied this question.
www.synapsesocial.com/papers/6a057ddd127e0d5a54a22519 — DOI: https://doi.org/10.1039/d0cc04579a